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[1]张迎亚,张利雄.金属有机骨架材料成型的研究进展[J].南京工业大学学报(自然科学版),2018,40(06):124-130.[doi:10.3969/j.issn.1671-7627.2018.06.019]
 ZHANG Yingya,ZHANG Lixiong.Review on shaping methods of metal-organic frameworks[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),2018,40(06):124-130.[doi:10.3969/j.issn.1671-7627.2018.06.019]
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金属有机骨架材料成型的研究进展()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
40
期数:
2018年06期
页码:
124-130
栏目:
出版日期:
2018-11-20

文章信息/Info

Title:
Review on shaping methods of metal-organic frameworks
文章编号:
1671-7627(2018)06-0124-07
作者:
张迎亚张利雄
南京工业大学 化工学院 材料化学工程国家重点实验室,江苏 南京 210009
Author(s):
ZHANG YingyaZHANG Lixiong
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering,Nanjing Tech University,Nanjing 210009,China
关键词:
金属有机骨架 成型方法 杂化多孔固体材料
Keywords:
MOFs shaping method hybrid porous solid material
分类号:
TB383;O641.4;O635
DOI:
10.3969/j.issn.1671-7627.2018.06.019
文献标志码:
A
摘要:
金属有机骨架材料(MOFs)是由无机金属离子或离子簇与有机配体通过配位键自组装而成的有机-无机杂化多孔固体材料。一般采用水热或溶剂热法制备,产品为微米或亚微米尺度大小的晶体,不适宜于规模化工业应用,需要将其构建成成型体。由于MOFs材料组成上的特殊性,尚缺乏统一的普适性成型方法。本文综述了MOFs成型方法,主要包括共混成型法、原位生长法及高内相乳液法。根据固化方式及实验过程的不同,共混成型法又可分为溶胶-凝胶法、静电纺丝法; 原位生长法可分为一步合成法、逐步法以及层叠层法。最后从负载量、适用范围、MOFs分散的均匀性以及成型前后对MOFs性质的影响等方面,对这几种成型方法进行比较,并对MOFs成型体制备的方法作出展望。
Abstract:
Metal-organic frameworks(MOFs)are new kinds of porous solid materials made from self-assembly of metal ions or ion clusters bridged with organic linkers.They are commonly synthesized by solvothermal synthesis,obtaining particles with sizes of submicron or micrometers.This makes them difficult for industrial application.Various methods have been developed to process MOF crystals to shapeable monolith or materials.However,because of the special organic-inorganic coordinated structure,there are still no effective strategy for the shaping of MOFs.The shaping methods including blending,in situ synthesis and synthesis in high internal phase emulsions,were introduced.Based on curing methods and experimental processes,sol-gel and electrostatic spinning techniques were commonly used in blending,and one step,stepwise and layer-by-layer methods were applied in in situ technique.The difference among these shaping methods were compared in aspect of the loadings,applicable scope,uniformity of MOFs dispersion,and the influence on properties after shaping,and the direction to the development of new shaping methods for MOFs was envisioned.

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备注/Memo

备注/Memo:
收稿日期:2017-05-22
作者简介:张迎亚(1991—),男,安徽宿州人,硕士,主要研究方向为粉体成型; 张利雄(联系人),教授,E-mail:lxzhangnjut@gmail.com.
引用本文:张迎亚,张利雄.金属有机骨架材料成型的研究进展[J].南京工业大学学报(自然科学版),2018,40(6):124-130..
更新日期/Last Update: 2018-11-30