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[1]仇龙云,李力成,冯新,等.基材预处理方式对Cu3(BTC)2成膜的影响[J].南京工业大学学报(自然科学版),2014,36(01):7-12.[doi:10.3969/j.issn.1671-7627.2014.01.002]
 QIU Longyun,LI Licheng,FENG Xin,et al.Effects of substrate pretreatment on Cu3(BTC) 2 film preparation[J].Journal of NANJING TECH UNIVERSITY(NATURAL SCIENCE EDITION),2014,36(01):7-12.[doi:10.3969/j.issn.1671-7627.2014.01.002]
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基材预处理方式对Cu3(BTC)2成膜的影响()
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《南京工业大学学报(自然科学版)》[ISSN:1671-7627/CN:32-1670/N]

卷:
36
期数:
2014年01期
页码:
7-12
栏目:
出版日期:
2014-01-20

文章信息/Info

Title:
Effects of substrate pretreatment on Cu3(BTC) 2 film preparation
文章编号:
1671-7627(2014)01-0007-06
作者:
仇龙云李力成冯新付双钦张所瀛陆小华杨祝红
南京工业大学 化学化工学院 材料化学工程国家重点实验室,江苏 南京 210009
Author(s):
QIU LongyunLI LichengFENG XinFU ShuangqinZHANG SuoyingLU XiaohuaYANG Zhuhong
State Key Laboratory of Materials-oriented Chemical Engineering,College of Chemistry and Chemical Engineering,Nanjing University of Technology,Nanjing 210009,China
关键词:
Cu3(BTC)2 预处理 Piranha溶液 UV Ti材
Keywords:
Cu3(BTC)2 film pretreatment Piranha solution UV titanium
分类号:
O647
DOI:
10.3969/j.issn.1671-7627.2014.01.002
文献标志码:
A
摘要:
采用原位水热法在不同方式预处理的Ti材上制备Cu3(BTC)2(H3BTC为C9H6O6,均苯三甲酸)膜。通过扫描电子显微镜(SEM)、原子力显微镜(AFM)、X线衍射仪(XRD)等表征手段详细考察预处理方式对Cu3(BTC)2成膜的影响。结果表明:紫外光照射能有效提高Ti材表面的羟基化程度,从而有利于Cu3(BTC)2晶体在表面生长; 相比紫外光预处理,Piranha溶液预处理的表面更适合Cu3(BTC)2晶体的生长; 在Piranha溶液结合紫外光照射处理的Ti材表面能制备出较连续的Cu3(BTC)2膜。
Abstract:
Cu3(BTC)2(H3BTC=benzene-1,3,5-tricarboxylic acid)films on different pretreated Ti substrates were prepared by the in-situ hydrothermal synthesis method.The effects of pretreatment on the film preparation were investigated by scanning electron microscopy(SEM),atomic force microscope(AFM)and X-Ray powder diffraction(XRD).Results showed that UV irradiation could improve hydroxylation of titanium surface,which was beneficial for Cu3(BTC)2 growth.Compared with UV pretreatment,the surface pretreated by Piranha solution was more suitable for Cu3(BTC)2 growth.Cu3(BTC)2 film was fabricated on the Ti substrate pretreated by Piranha solution combination with UV irradiation.

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备注/Memo

备注/Memo:
收稿日期:2013-04-16
基金项目:国家重点基础研究计划(973计划)(2013CB733503); 国家自然科学重点基金(21136001,21136004); 国家高技术研究发展计划(863计划)(2006AA03Z455)
作者简介:仇龙云(1988—),女,江苏盐城人,硕士生,主要研究方向为金属有机骨架(MOFs)膜; 杨祝红(联系人),副研究员,E-mail:zhhyang@njut.edu.cn..
更新日期/Last Update: 2014-01-20